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BaxSr1-xTiO3微弧氧化铁电薄膜微观结构及电学性能

王敏 李文芳 张果戈 王晓军 唐鹏

王敏, 李文芳, 张果戈, 王晓军, 唐鹏. BaxSr1-xTiO3微弧氧化铁电薄膜微观结构及电学性能[J]. 电子科技大学学报, 2015, 44(5): 778-783. doi: 10.3969/j.issn.1001-0548.2015.05.023
引用本文: 王敏, 李文芳, 张果戈, 王晓军, 唐鹏. BaxSr1-xTiO3微弧氧化铁电薄膜微观结构及电学性能[J]. 电子科技大学学报, 2015, 44(5): 778-783. doi: 10.3969/j.issn.1001-0548.2015.05.023
WANG Min, LI Wen-fang, ZHANG Guo-ge, WANG Xiao-jun, . Microstructure and Electrical Property of BaxSr1-xTiO3 Ferroelectric Thin Film Prepared by Microarc Oxidation[J]. Journal of University of Electronic Science and Technology of China, 2015, 44(5): 778-783. doi: 10.3969/j.issn.1001-0548.2015.05.023
Citation: WANG Min, LI Wen-fang, ZHANG Guo-ge, WANG Xiao-jun, . Microstructure and Electrical Property of BaxSr1-xTiO3 Ferroelectric Thin Film Prepared by Microarc Oxidation[J]. Journal of University of Electronic Science and Technology of China, 2015, 44(5): 778-783. doi: 10.3969/j.issn.1001-0548.2015.05.023

BaxSr1-xTiO3微弧氧化铁电薄膜微观结构及电学性能

doi: 10.3969/j.issn.1001-0548.2015.05.023
详细信息
  • 中图分类号: TB34;TN384

Microstructure and Electrical Property of BaxSr1-xTiO3 Ferroelectric Thin Film Prepared by Microarc Oxidation

  • 摘要: 用分析纯Ba(OH)2·8H2O和Sr(OH)2·8H2O配制电解液,采用微弧氧化法在工业纯钛板(99.5%)表面原位生成BaxSr(1-x)TiO3铁电薄膜。研究了Ba2+/Sr2+对薄膜晶体结构、物相组成、表面形貌及表面粗糙度的影响,并对薄膜的介电、铁电性能进行了表征。结果表明,Ba2+/Sr2+对薄膜晶体结构无影响,但随Ba2+含量增加,BaxSr(1-x)TiO3薄膜中x值与理论值偏离越大;随电解液浓度及Ba2+/Sr2+增加,薄膜表面变得疏松,散布的颗粒尺寸增大,表面粗糙度值增加。在Ba2+和Sr2+各为0.2 mol/L时所得薄膜表面平整度及致密性最好,表面粗糙度值最小,其在100 Hz条件下的介电常数为454.8,且具有饱和电滞回线,有较好的商业化应用前景。
  • [1] LEE Sang-woon, HAN Jeong-hwan, HAN Sora, et al. Atomic layer deposition of SrTiO3 thin films with highly enhanced growth rate for ultrahigh density capacitors[J]. Chemistry of Materials, 2011, 23(8): 2227-2236.
    [2] MANCILLA J E, RIVERA J N, HERMANDEZ C A, et al. Influence of substrate temperature on morphological and ferroelectric properties of Ba0.75Sr0.25TiO3 thin films deposited on nichrome substrates by RF sputtering[J]. Ceramics International, 2013, 39(6): 7167-7172.
    [3] ZHOU X, SAZEGAR M, STEMME F, et al. Correlation of the microstructure and microwave properties of Ba0.6Sr0.4TiO3 thick-films[J]. Journal of the European Ceramic Society, 2012, 32(16): 4311-4318.
    [4] NEDELCU L, IOACHIM A, TOACSAN M, et al. Synthesis and dielectric characterization of Ba0.6Sr0.4TiO3 ferroelectric ceramics[J]. Thin Solid Films, 2011, 519(17): 5811-5815.
    [5] XU Zun-ping, QIANG Hua, CHEN Yi, et al. Effects of sintering temperature on the properties of donor-acceptor codoped Ba0.67Sr0.33TiO3 ceramics for pyroelectric infrared detector applications[J]. Ceramics International, 2014, 40(3): 4617-4621.
    [6] JIANG Wei-hai, CAI Wei, LIN Ze-bin, et al. Effects of Nd-doping on optical and photovoltaic properties of barium titanate thin films prepared by sol-gel method[J]. Materials Research Bulletin, 2013, 48(9): 3092-3097.
    [7] YU Yang, WANG Xu-sheng, YAO Xi . Dielectric properties of Ba1-xSrxTiO3 ceramics prepared by microwave sintering[J]. Ceramics International, 2013, 39(9): S335-S339
    [8] LIU Cheng, LIU Peng. Microstructure and dielectric properties of BST ceramics derived from high-energy ball-milling[J]. Journal of Alloys and Compounds, 2014(584): 114-118.
    [9] ZHU Guis-heng, YANG Zu-pei, XU Hua-rui. The properties of Ba0.5Sr0.5TiO3 thin film prepared by RF magnetron sputtering from powder target[J]. Vacuum, 2012, 86(12): 1883-1885.
    [10] FUENTES S, CHÁVEZ E, PADILLA-CAMPOS L, et al. Influence of reactant type on the Sr incorporation grade and structural characteristics of Ba1-xSrxTiO3 (x=0,1) grown by sol-gel-hydrothermal synthesis[J]. Ceramics International, 2013, 39(8): 8823-8831.
    [11] KAVEH A, SEYED-MOHAMMAD M, ALI N, et al. Electronic structure and morphological study of BaTiO3 film grown by pulsed-laser deposition[J]. Materials Letters, 2012(72): 107-109.
    [12] SBROCKEY N M,COLE M W, KALKUR T S,et al. MOVCD growth of compositionally graded BaxSr1-xTiO3 thin films[J]. Integrated Ferroelectrics: An International Journal, 2011, 126(1): 21-27.
    [13] MEGURU T, MASAKAZU I .Plasma-induced degradation of aniline in aqueous solution[J]. Thin Solid Films, 2001, 386(2): 204-207.
    [14] SHIN Young-keun, CHAE Won-seok, SONG Yong-won, et al. Formation of titania photocatalyst films by microarc oxidation of Ti and Ti6Al4V alloys[J]. Electrochemistry Communications, 2006, 8(3): 465-470 .
    [15] HONG Min-ho, LEE Dong-hyun, KIM Kwang-mahn, et al. Study on bioactivity and bonding strength between Ti alloy substrate and TiO2 film by microarc oxidation[J] Thin Solid Films, 2011, 519(20): 7065-7070.
    [16] GNEDENKOV S V, GORDIENKO P S, KHRISANFOVA O A, et al. Formation of BaTiO3 coating on titante by microarc oxidation method[J]. Journal of Materials Science, 2002(37): 2263-2265.
    [17] 姜兆华, 李文旭, 闫久春, 等. 微等离子体氧化法制备 钛酸钡陶瓷膜[J]. 材料工程, 2002(2): 34-37. JIANG Zhao-hua, LI Wen-xu, YAN Jiu-chun, et al. Fabrication of barium titanate thin films by microplasma oxidation[J]. Journal of Materials Engineering, 2002(2): 34-37.
    [18] WU Chu-tsun, LU Fu-hsing. Sythesis of barium titanate films by plasma electrolytic oxidation at room electolyte temperature[J]. Surface & Coatings Technology, 2005, 199(2-3): 225-230.
    [19] 王新华, 赵晓云. 钛酸钡膜的制备、结构及结合强度[J]. 压电与声光, 2011, 33(1): 143-146. WANG Xing-hua, ZHAO Xiao-yun. Preparation of barium titanate films and its structural characterization and adhesive strength[J]. Piezoelectrics & Acoustooptics, 2011, 33(1) : 143-146.
    [20] 韩冰. 微弧氧化法沉积BaTiO3铁电薄膜的研究[D]. 广州: 华南理工大学, 2007. HAN Bing. The study of deposition technology of BaTiO3 ferroelectric films by microarc oxidation[D]. Guang Zhou: South China University of Technology, 2007.
    [21] 黄文波. 微弧氧化法生成ABO3型铁电薄膜研究[D]. 广 州: 华南理工大学, 2010. HUANG Wen-bo. Deposition of ABO3-type ferroelectric films by microarc Oxidation[D]. Guang Zhou: South China University of Technology, 2010.
    [22] 王敏, 郭会勇, 张果戈, 等. Ba0.5Sr0.5TiO3铁电薄膜的微 弧氧化成膜研究[J]. 表面技术, 2013, 42(4): 35-38. WANG Min, GUO Hui-yong, ZHANG Guo-ge, et al. Formation of Ba0.5Sr0.5TiO3 ferroelectric film by microarc oxidation[J]. Surface Technology, 2013, 42(4): 35-38.
    [23] XUE Wen-bin, DENG Zhi-wei, CHEN Ru-yi, et al. Microstructure and properties of ceramic coatings produced on 2024 aluminum alloy by microarc oxidation[J]. Journal of Materials Science, 2001, 36(11): 2615-2619.
    [24] 钟维烈. 铁电体物理学[M]. 北京: 科学出版社, 1996: 130-142. ZHONG Wei-lie. Ferroelectric physics[M]. Beijing: Science Press, 1996: 130-142.
    [25] XUE Wen-bin, WANG Chao, CHEN Ru-yi, et al. Structure and properties characterization of ceramic coatings produced on Ti-6Al-4V alloy by microarc oxidation in aluminate solution[J]. Materials Letters, 2002, 52(6): 435-441.
    [26] MOHAMMED E M, MALINI K A, KURIAN Philip, et al. Modification of dielectric and mechanical properties of rubber ferrite composites containing manganese zinc ferrite[J]. Materials Research Bulletin, 2002, 37(2): 753-768.
    [27] 李翔, 严彪, 董刚. Sr掺杂对BaTiO3陶瓷结构与介电性能 的影响[J]. 材料热处理学报, 2009, 30(5): 23-25. LI Xiang, YAN Biao, DONG Gang. Effect of Sr doping on structure and dielectric properties of BaTiO3 ceramics[J]. Transactions of Materials and Heat Treatment, 2009, 30(5): 23-25.
    [28] 王国强, 王安福, 王邵明. Sol-Gel法制备BST铁电薄膜 及性能研究[J]. 武汉理工大学学报, 2007, 29(5): 10-12. WANG Guo-qiang, WANG An-fu, WANG Shao-ming. Research on the preparation of BST ferroelectric thin films by Sol-Gel and its properties[J]. Journal of Wuhan University of Technology, 2007, 29(5): 10-12.
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BaxSr1-xTiO3微弧氧化铁电薄膜微观结构及电学性能

doi: 10.3969/j.issn.1001-0548.2015.05.023
  • 中图分类号: TB34;TN384

摘要: 用分析纯Ba(OH)2·8H2O和Sr(OH)2·8H2O配制电解液,采用微弧氧化法在工业纯钛板(99.5%)表面原位生成BaxSr(1-x)TiO3铁电薄膜。研究了Ba2+/Sr2+对薄膜晶体结构、物相组成、表面形貌及表面粗糙度的影响,并对薄膜的介电、铁电性能进行了表征。结果表明,Ba2+/Sr2+对薄膜晶体结构无影响,但随Ba2+含量增加,BaxSr(1-x)TiO3薄膜中x值与理论值偏离越大;随电解液浓度及Ba2+/Sr2+增加,薄膜表面变得疏松,散布的颗粒尺寸增大,表面粗糙度值增加。在Ba2+和Sr2+各为0.2 mol/L时所得薄膜表面平整度及致密性最好,表面粗糙度值最小,其在100 Hz条件下的介电常数为454.8,且具有饱和电滞回线,有较好的商业化应用前景。

English Abstract

王敏, 李文芳, 张果戈, 王晓军, 唐鹏. BaxSr1-xTiO3微弧氧化铁电薄膜微观结构及电学性能[J]. 电子科技大学学报, 2015, 44(5): 778-783. doi: 10.3969/j.issn.1001-0548.2015.05.023
引用本文: 王敏, 李文芳, 张果戈, 王晓军, 唐鹏. BaxSr1-xTiO3微弧氧化铁电薄膜微观结构及电学性能[J]. 电子科技大学学报, 2015, 44(5): 778-783. doi: 10.3969/j.issn.1001-0548.2015.05.023
WANG Min, LI Wen-fang, ZHANG Guo-ge, WANG Xiao-jun, . Microstructure and Electrical Property of BaxSr1-xTiO3 Ferroelectric Thin Film Prepared by Microarc Oxidation[J]. Journal of University of Electronic Science and Technology of China, 2015, 44(5): 778-783. doi: 10.3969/j.issn.1001-0548.2015.05.023
Citation: WANG Min, LI Wen-fang, ZHANG Guo-ge, WANG Xiao-jun, . Microstructure and Electrical Property of BaxSr1-xTiO3 Ferroelectric Thin Film Prepared by Microarc Oxidation[J]. Journal of University of Electronic Science and Technology of China, 2015, 44(5): 778-783. doi: 10.3969/j.issn.1001-0548.2015.05.023
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